Guide to Potassium manganate(VII) titration· For KMnO4 titration, no indicator is added because KMnO4 acts as its own indicator and it would change to pale pink colour at the end point.
· KMnO4 titration is used to determine the concentration of Fe2+ (Iron(II) ions) , H2O2 (hydrogen peroxide) and C2O42- (ethanedioate).
· KMnO4 titrations must be carried out in acidified condition because in neutral or alkaline solution, brown solid MnO2 is formed and as a result it would be difficult to detect the end point.
· To acidify, sulphuric acid is used and not other acids such as hydrochloric acid and nitric acid because the chloride ions or nitrate ions would also be oxidised.
· Most KMnO4 titrations should be carried out at room temperature except titration involving C2O42- which is normally carried out at 70 oC. For ethanediote, any temperature lower than 70 oC could cause the precipitation of MnO2.
· Titration using KMnO4 solution should be carried out slowly. A brown precipitate of MnO2 is formed when KMnO4 is dropped from the burette too quickly.
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Guide to Iodine-thiosulphate titration
· Starch is used as an indicator in this titration
· The starch solution should not be added at the beginning of the titration. The reason is at this stage, there is a high concentration of iodine and iodine would be adsorbed onto the starch molecule.
· The starch solution should be added towards the end of the titration when the reaction mixture turns pale yellow. (Warning: not too pale as you may overshot the endpoint)
· The starch solution will produce a dark blue colour with iodine.
· At the end point ,the solution turns colourless.
· Be careful, the solution may become blue again due to the atmospheric oxidation of iodide (from potassium iodide). You shouldn’t continue titrating again.